Sintesis Senyawa C-Vanillin Kaliks[4]resorsinarena dan Uji Aplikasinya sebagai Adsorben Ion Fe³⁺: Studi Optimasi pH Sintesis Senyawa C-Vanillin Kaliks[4]resorsinarena dan Uji Aplikasinya sebagai Adsorben Ion Fe³⁺: Studi Optimasi pH

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Page Numbers: 1834-1843
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Published: Jul 9, 2025
Digital Object Identifier: 10.58578/masaliq.v5i4.6632
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Authors:
Nurul Afifah1*, Sri Benti Etika2
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Nurul Afifah
Universitas Negeri Padang
Sri Benti Etika
Universitas Negeri Padang

Abstract

This study is driven by the need for selective and efficient adsorbent materials to address heavy metal ion contamination, particularly Fe³⁺, in aquatic environments. The aim of this research is to synthesize C-vanillin calix[4]resorcinarene and evaluate its potential as an adsorbent for Fe³⁺ ions, with a specific focus on optimizing pH as a key parameter in the adsorption process. The compound was synthesized via a reflux method, yielding a solid product weighing 3.9726 grams. Structural characterization was performed using Thin-Layer Chromatography (TLC), FTIR spectroscopy, and melting point analysis. TLC results showed a single spot for each compound, indicating high purity. The FTIR spectrum confirmed the presence of characteristic functional groups, with absorption bands at 3355 cm⁻¹ (O–H), 1605 cm⁻¹ (aromatic C=C), 1426 cm⁻¹ (C–H), and 1211 cm⁻¹ (C–O). The high melting point range of 383–384 °C suggests thermal stability and the formation of a new structure. Adsorption tests for Fe³⁺ ions were conducted across a pH range of 1–6, revealing increased adsorption efficiency with rising pH and a maximum value of 1.9015 mg/g at pH 5. A decline in efficiency was observed at pH 6. The study concludes that C-vanillin calix[4]resorcinarene demonstrates promising selectivity and efficiency as an Fe³⁺ ion adsorbent under specific pH conditions and possesses physicochemical properties conducive to practical applications in water purification.

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How to Cite
Afifah, N., & Etika, S. B. (2025). Sintesis Senyawa C-Vanillin Kaliks[4]resorsinarena dan Uji Aplikasinya sebagai Adsorben Ion Fe³⁺: Studi Optimasi pH. MASALIQ, 5(4), 1834-1843. https://doi.org/10.58578/masaliq.v5i4.6632

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