Optimasi Kecepatan Pengadukan pada Biosorpsi Methyl Orange Menggunakan Kulit Lengkeng Termodifikasi Putih Telur Itik Optimization of Agitation Speed in Methyl Orange Biosorption Using Longan Peel Modified with Duck Egg White

Crossmark

Main Article Content


Abstract

Although various lignocellulosic biomasses have been developed as biosorbents for dye removal, the use of longan peel modified with duck egg white for Methyl Orange biosorption, particularly in relation to the effect of agitation speed, remains limited. This study aimed to determine the optimum agitation speed for Methyl Orange biosorption using longan peel modified with duck egg white in a batch system. The study employed a quantitative approach with a laboratory experimental design. The characteristics of the biosorbent were analyzed using Fourier-transform infrared (FTIR) spectroscopy, while the Methyl Orange concentration was determined using a UV–Vis spectrophotometer. The results showed that agitation speed affected biosorption performance. The optimum condition was achieved at 200 rpm, with the highest adsorption capacity of 66.47 mg/g. FTIR analysis confirmed the successful modification of the biosorbent through the addition of protein functional groups to the longan peel surface. The FTIR spectrum after biosorption also showed the presence of sulfonate (S=O) groups, indicating the adsorption of Methyl Orange. These findings demonstrate that protein modification and an appropriate agitation speed can enhance the performance of lignocellulosic biomass-based biosorbents in adsorbing anionic dyes. This study contributes to the development of potentially environmentally friendly and low-cost biosorbents for wastewater treatment and provides a basis for optimizing the biosorption process. Future research should investigate adsorption kinetics and isotherms, biosorbent regeneration, and its application to actual industrial wastewater.

Keywords:
Share Article:

Citation Metrics:

Scopus

Downloads

Download data is not yet available.

Citation Metrics & Similar Scopus Articles

Data source Crossref
0
citations
Citation counts are source-specific and may differ because database coverage, reference matching, and update schedules are different. Counts are not added together. Crossref values represent citation links registered and matched by Crossref.
Check Secondary Documents in Scopus
Open this article in Scopus, then check the Secondary documents tab. Use Manual Citation Fallback only for counts you have verified manually.
Open in Scopus
Similar Scopus Articles
Scopus
  1. Rakhimov S. (2027)
    An eco-friendly sorption–spectrophotometric method for Pb(II) determination in wastewater based on methyl thymol blue immobilized on silk fibroin
    Talanta, 312
  2. Wang F. (2027)
    Implications for Advanced HED Fuel Design: Electronic and Spectroscopic Signatures of Methyl–Substituted Adamantanes
    Fuel, 429
  3. Chen Y. (2027)
    In-Situ N-doped Carbon-Supported Ru-Fe catalysts for green diesel production from Styrax confusus fruit oil via hydrodeoxygenation
    Fuel, 429

Article Details

How to Cite
Pratiwi, P. A., & Kurniawati, D. (2026). Optimasi Kecepatan Pengadukan pada Biosorpsi Methyl Orange Menggunakan Kulit Lengkeng Termodifikasi Putih Telur Itik. MASALIQ, 6(5), 2658-2671. https://doi.org/10.58578/masaliq.v6i5.11747

References

Abbas, M., & Trari, M. (2024). Adsorption behavior of methylene blue onto activated coconut shells: Kinetic, thermodynamic, mechanism and regeneration of the adsorbent. Dose-Response, 22(4), Article 15593258241290708. https://doi.org/10.1177/15593258241290708

Chollakup, R., Kongtud, W., Sukatta, U., Premchookiat, M., Piriyasatits, K., Nimitkeatkai, H., & Jarerat, A. (2021). Eco-friendly rice straw paper coated with longan (Dimocarpus longan) peel extract as bio-based and antibacterial packaging. Polymers, 13(18), Article 3096. https://doi.org/10.3390/polym13183096

Dehmani, Y., El-Kordy, A., Georgin, J., Franco, D. S. P., Ba Mohammed, B., Schaefer, S., Dehbi, A., Tijani, N., Lamhasni, T., & Abouarnadasse, S. (2026). Synthesis and characterization of novel chitosan–clay coated iron oxide nanoparticles for optimized adsorption and mechanistic study of methyl orange in industrial wastewater. International Journal of Biological Macromolecules, 347, Article 150568. https://doi.org/10.1016/j.ijbiomac.2026.150568

Delgado, R. (2022). Misuse of Beer–Lambert law and other calibration curves. Royal Society Open Science, 9(2), Article 211103. https://doi.org/10.1098/rsos.211103

Franco, L. C., Nishi, L., Scaliante, M. H. N. O., & Cusioli, L. F. (2026). Treatments for textile wastewater: Perspectives from studies using supercritical water and biomass-based activated carbon—A review. Processes, 14(6), Article 885. https://doi.org/10.3390/pr14060885

Gajendiran, V., Deivasigamani, P., Sivamani, S., & Sivakumar, P. M. (2023). A review on cassava residues as adsorbents for removal of organic and inorganic contaminants in water and wastewater. Journal of Chemistry, 2023, Article 7891518. https://doi.org/10.1155/2023/7891518

Hoa, N. T. H., Quynh, N. T., Nguyen, V. D., Nguyen, T. N., Huy, B. Q., Thanh, N. T., Loan, H. T., Hoa, N. T. Q., & Nghia, N. T. (2025). Adsorptive removal of Reactive Black 5 by longan peel-derived activated carbon: Kinetics, isotherms, thermodynamics, and modeling. Water, 17(11), Article 1678. https://doi.org/10.3390/w17111678

Irawati, H., Aprilita, N. H., & Sugiharto, E. (2018). Adsorpsi Zat Warna Kristal Violet Menggunakan Limbah Kulit Singkong (Manihot esculenta). Berkala MIPA, 25(1), 17–31. https://journal.ugm.ac.id/bimipa/article/view/17940

Islam, M. M., Aidid, A. R., Mohshin, J. N., Mondal, H., Ganguli, S., & Chakraborty, A. K. (2025). A critical review on textile dye-containing wastewater: Ecotoxicity, health risks, and remediation strategies for environmental safety. Cleaner Chemical Engineering, 11, Article 100165. https://doi.org/10.1016/j.clce.2025.100165

Kamaru, A. A., Sani, N. S., & Malek, N. A. N. N. (2016). Raw and surfactant-modified pineapple leaf as adsorbent for removal of methylene blue and methyl orange from aqueous solution. Desalination and Water Treatment, 57(40), 18836–18850. https://doi.org/10.1080/19443994.2015.1095122

Khan, A. U., Zahoor, M., Rehman, M. U., Shah, A. B., Zekker, I., Khan, F. A., Ullah, R., Albadrani, G. M., Bayram, R., & Mohamed, H. R. H. (2022). Biological mineralization of methyl orange by Pseudomonas aeruginosa. Water, 14(10), Article 1551. https://doi.org/10.3390/w14101551

Kostjukov, V. (2026). Excitation of three forms of methyl orange dye in aqueous solution: A comparative theoretical analysis. Journal of Photochemistry and Photobiology A: Chemistry, 478, Article 117205. https://doi.org/10.1016/j.jphotochem.2026.117205

Li, M., Hou, X., Lin, L., Jiang, F., Qiao, D., & Xie, F. (2023). Legume protein/polysaccharide food hydrogels: Preparation methods, improvement strategies and applications. International Journal of Biological Macromolecules, 243, Article 125217. https://doi.org/10.1016/j.ijbiomac.2023.125217

Ma, J., Hou, L., Li, P., Zhang, S., & Zheng, X. (2022). Modified fruit pericarp as an effective biosorbent for removing azo dye from aqueous solution: Study of adsorption properties and mechanisms. Environmental Engineering Research, 27(2), Article 200634. https://doi.org/10.4491/eer.2020.634

Malbenia John, M., Benettayeb, A., Belkacem, M., Ruvimbo Mitchel, C., Hadj Brahim, M., Benettayeb, I., Haddou, B., Al-Farraj, S., Alkahtane, A. A., Ghosh, S., Chia, C. H., Sillanpää, M., Baigenzhenov, O., & Hosseini-Bandegharaei, A. (2024). An overview on the key advantages and limitations of batch and dynamic modes of biosorption of metal ions. Chemosphere, 357, Article 142051. https://doi.org/10.1016/j.chemosphere.2024.142051

Mayerhöfer, T. G., Pahlow, S., & Popp, J. (2020). The Bouguer–Beer–Lambert law: Shining light on the obscure. ChemPhysChem, 21(18), 2029–2046. https://doi.org/10.1002/cphc.202000464

Mnyango, J. I., Nyoni, B., Phiri, C., Fouda-Mbanga, B. G., Amusat, S. O., Maringa, A., Yalala-Ndlovu, B., Hlabano-Moyo, B., Tywabi-Ngeva, Z., & Hlangothi, S. P. (2025). Sustainable wastewater treatment: Mechanistic, environmental, and economic insights into biochar for synthetic dye removal. Next Materials, 9, Article 100974. https://doi.org/10.1016/j.nxmate.2025.100974

Mohadi, R., Normah, N., Fitri, E. S., & Palapa, N. R. (2022). Unique adsorption properties of cationic dyes malachite green and Rhodamine B on longan (Dimocarpus longan) peel. Science and Technology Indonesia, 7(1), 115–125. https://doi.org/10.26554/sti.2022.7.1.115-125

Osman, A. I., Abd El-Monaem, E. M., Elgarahy, A. M., Aniagor, C. O., Hosny, M., Farghali, M., Rashad, E., Ejimofor, M. I., López-Maldonado, E. A., Ihara, I., Yap, P.-S., Rooney, D. W., & Eltaweil, A. S. (2023). Methods to prepare biosorbents and magnetic sorbents for water treatment: A review. Environmental Chemistry Letters, 21(4), 2337–2398. https://doi.org/10.1007/s10311-023-01603-4

Putra, A., Fauzia, S., Deswati, D., Arief, S., & Zein, R. (2024). The potential of duck egg white as a modifier for activated rice straw to enhance Cr(VI) ions adsorption in an aqueous solution. South African Journal of Chemical Engineering, 48, 204–213. https://doi.org/10.1016/j.sajce.2024.02.002

Ramadhani, E. D., & Kurniawati, D. (2021). Effect of contact time and agitation speed on the adsorption process of methylene blue dyes using longan shell (Euphoria longan L.) as biosorbent. American Journal of Sciences and Engineering Research, 4(6), 143–149. https://iarjournals.com/upload/46143149.pdf

Rattanavijit, U., Chaipetch, W., Salae, N., & Khaekta, P. (2022). Adsorption of fabric dye from synthetic wastewater by using agricultural waste as biosorbent. Journal of Vocational Education in Agriculture, 6(1), 39–50. https://li01.tci-thaijo.org/index.php/JVIA/article/view/253303

Sambang, L. M., Kenne Dedzo, G., Rigolet, S., & Ngameni, E. (2023). Solvent-free functionalization of sawdust with quaternary ammonium groups: Application to the biosorption of two anionic dyes. Sustainable Chemistry and Pharmacy, 33, Article 101068. https://doi.org/10.1016/j.scp.2023.101068

Tsoutsa, E. K., Tolkou, A. K., Kyzas, G. Z., & Katsoyiannis, I. A. (2024). An update on agricultural wastes used as natural adsorbents or coagulants in single or combined systems for the removal of dyes from wastewater. Water, Air, & Soil Pollution, 235(3), Article 178. https://doi.org/10.1007/s11270-024-06979-9

Wang, Y., Li, Y., Yang, Y., Jiang, B., Li, D., Liu, C., & Feng, Z. (2023). A novel adsorbent drived from salted egg white for efficient removal of cationic organic dyes from wastewater. Journal of Molecular Liquids, 372, Article 121210. https://doi.org/10.1016/j.molliq.2023.121210

Wu, L., Liu, X., Lv, G., Zhu, R., Tian, L., Liu, M., Li, Y., Rao, W., Liu, T., & Liao, L. (2021). Study on the adsorption properties of methyl orange by natural one-dimensional nano-mineral materials with different structures. Scientific Reports, 11(1), Article 10640. https://doi.org/10.1038/s41598-021-90235-1

Yadav, M., Singh, N., Annu, Khan, S. A., Raorane, C. J., & Shin, D. K. (2024). Recent advances in utilizing lignocellulosic biomass materials as adsorbents for textile dye removal: A comprehensive review. Polymers, 16(17), Article 2417. https://doi.org/10.3390/polym16172417

Yan, Y., Hang, F., Wei, T., Xie, C., & Niu, D. (2022). Modification of ovalbumin by Maillard reaction: Effect of heating temperature and different monosaccharides. Frontiers in Nutrition, 9, Article 914416. https://doi.org/10.3389/fnut.2022.914416

Yolanda, A. T., & Kurniawati, D. (2026). Pengaruh Kecepatan Pengadukan pada Biosorpsi Direct Blue 86 oleh Kulit Kelengkeng Termodifikasi. MASALIQ: Jurnal Pendidikan dan Sains, 6(3), 1190–1203. https://ejournal.yasin-alsys.org/masaliq/article/view/9912

Yu, B., Guo, M., Dong, H., Pei, J., Wan, X., & Xiang, S. (2025). MgAl layered double oxide: A promising adsorbent for effective methyl orange removal from wastewater. Journal of the Indian Chemical Society, 102(12), Article 102274. https://doi.org/10.1016/j.jics.2025.102274

Zein, R., Hevira, L., Zilfa, Rahmayeni, Fauzia, S., & Ighalo, J. O. (2023). The improvement of indigo carmine dye adsorption by Terminalia catappa shell modified with broiler egg white. Biomass Conversion and Biorefinery, 13(15), 13795–13812. https://doi.org/10.1007/s13399-021-02290-3

Most read articles by the same author(s)

1 2 > >>