Pengaruh pH terhadap Koagulasi Mikroplastik Polyethylene Terephthalate (PET) menggunakan Kitosan dari Cangkang Kepiting (Scylla serrata) Effect of pH on the Coagulation of Polyethylene Terephthalate (PET) Microplastics Using Chitosan from Crab Shells (Scylla serrata)

Crossmark

Main Article Content


Abstract

Polyethylene Terephthalate (PET) microplastics are among the primary contaminants in aquatic environments and pose potential risks to human health. Coagulation is an effective method for reducing microplastics; however, conventional coagulants such as alum may leave harmful residues. This study aims to evaluate the effectiveness of chitosan synthesized from crab shell waste (Scylla serrata) as an eco-friendly biocoagulant in the coagulation of PET microplastics. Chitosan synthesis was carried out through three stages: demineralization, deproteinization, and deacetylation. The coagulation process was conducted under varying pH conditions (3, 5, 7, 9, and 11), with a chitosan dosage of 500 mg/L and a sedimentation time of 45 minutes. The results show that optimal conditions were achieved at pH 7, with microplastic removal efficiency reaching 98.4%. Characterization using Fourier Transform Infrared Spectroscopy (FTIR), Particle Size Analyzer (PSA), and stereo microscopy confirmed successful floc formation and active interaction between chitosan and microplastics. The study concludes that chitosan derived from crab shell waste has strong potential as an effective and environmentally friendly alternative coagulant for treating water contaminated with microplastics.

Downloads

Download data is not yet available.

Citation Metrics & Similar Scopus Articles

Data source Crossref
0
citations
Citation counts are source-specific and may differ because database coverage, reference matching, and update schedules are different. Counts are not added together. Crossref values represent citation links registered and matched by Crossref.
Check Secondary Documents in Scopus
Open this article in Scopus, then check the Secondary documents tab. Use Manual Citation Fallback only for counts you have verified manually.
Open in Scopus
Similar Scopus Articles
Scopus
  1. Iida T. (2027)
    Prepackaged Low-Residue Diet “Clear-Through” Reduces the Required Volume of Polyethylene Glycol Solution for Colonoscopy Preparation: An Exploratory Randomized Controlled Study
    Den Open, 7(1)
  2. Nakago T. (2027)
    Bio-coke derived from green tea leaf waste and poly(ethylene terephthalate): preparation, internal structure, and pyrolysis behavior
    Fuel, 428
  3. Ma P. (2027)
    Multi-objective evaluation of bio-oil production from biomass and polyethylene co-pyrolysis coupled with selective condensation using a combined weighting-TOPSIS method
    Fuel, 429

Article Details

How to Cite
HudaAli, H., & Dewata, I. (2025). Pengaruh pH terhadap Koagulasi Mikroplastik Polyethylene Terephthalate (PET) menggunakan Kitosan dari Cangkang Kepiting (Scylla serrata). MASALIQ, 5(4), 2109-2119. https://doi.org/10.58578/masaliq.v5i4.6875

References

A, R., Noor, E., & Suptijah, P. (2018). Pemanfaatan Kitosan Dalam Daur Ulang Air Sebagai Aplikasi. Jphpi, 21(2), 276–286.

Djaenudin, D., Budianto, E., Saepudin, E., & Nasir, M. (2019). Ekstraksi Kitosan Dari Cangkang Rajungan Pada Lama Dan Pengulangan Perendaman Yang Berbeda. Jurnal Teknologi Perikanan Dan Kelautan, 10(1), 49–59. https://doi.org/10.24319/jtpk.10.49-59

Eamrat, R., Rujakom, S., Pussayanavin, T., Taweesan, A., Witthayaphirom, C., & Kamei, T. (2024). Optimizing biocoagulant aid from shrimp shells (Litopenaeus vannamei) for enhancing microplastics removal from aqueous solutions. Environmental Technology and Innovation, 33(November 2023). https://doi.org/10.1016/j.eti.2023.103457

Fadhilah, N., Bafadal, M., & Sastyarina, Y. (2023). Pengaruh Beberapa Variasi Konsentrasi Kitosan Terhadap Potensial Zeta Nanopartikel Ekstrak Bawang Dayak (Eleutherine bulbosa). Proceeding of Mulawarman Pharmaceuticals Conferences, 18, 144–148. https://doi.org/10.25026/mpc.v18i1.718

Gao, Y., & Liu, Y. (2022). Removal of microplastics by coagulation treatment in waters and prospect of recycling of separated microplastics: A mini-review. Journal of Environmental Chemical Engineering, 10(5), 108197. https://doi.org/10.1016/j.jece.2022.108197

He, W., Tang, C., Wang, Z., Ke, S., & Lu, P. (2024). Treatment process of pre-coagulated waters involving polyethylene (PE) microplastics by ultrafiltration membranes coupled without or with pre-deposited aggregate-based layer. Journal of Environmental Chemical Engineering, 12(5). https://doi.org/10.1016/j.jece.2024.113964

Huang, L., He, W., Zhang, Y., Wang, X., Wu, K., Yang, Z., & Zhang, J. (2023). Chitosan enhances poly aluminum chloride flocculation system removal of microplastics: Effective, stable, and pollution free. Journal of Water Process Engineering, 54(2), 103929. https://doi.org/10.1016/j.jwpe.2023.103929

Hung, C., Klasios, N., Zhu, X., Sedlak, M., Sutton, R., & Rochman, C. M. (2021). Methods Matter: Methods for Sampling Microplastic and Other Anthropogenic Particles and Their Implications for Monitoring and Ecological Risk Assessment. Integrated Environmental Assessment and Management, 17(1), 282–291. https://doi.org/10.1002/ieam.4325

Husni, P., Junaedi, J., & Gozali, D. (2020). Potensi Kitosan Bersumber dari Limbah Cangkang Rajungan (Portunus pelagicus) dalam Bidang Farmasi. Majalah Farmasetika, 5(1), 32–38. https://doi.org/10.24198/mfarmasetika.v5i1.23804

Hutabarat, D. M., Witasari, W. S., & Baskoro, R. (2023). Pengaruh Jenis Koagulan Dan Variasi Ph Terhadap Kualitas Limbah Cair Di Instalasi Pengolahan Air Limbah Pt Kawasan Industri Intiland. DISTILAT: Jurnal Teknologi Separasi, 8(3), 588–594. https://doi.org/10.33795/distilat.v8i3.464

Ikrar Jamika, F., Dewata, I., Maharani, S., Primasari, B., & Dewilda, Y. (2023). Dampak Pencemaran Mikroplastik di Wilayah Pesisir Laut Impact of Microplastics Pollution in the Coastal Areas. Jurnal Sumberdaya Akuatik Indopasifik, 7(3), 337–344. https://doi.org/10.46252/jsai-fpik-unipa.2023.Vol.7.No.3.309

Kurniawan, Y. (2021). Efektivitas Limbah Cangkang Kepiting Sebagai Biokoagulan Dalam Penurunan Kadar Kekeruhan Dan Warna Air Baku Sungai Kapuas. Jurnal Teknologi Lingkungan Lahan Basah, 10(1), 001. https://doi.org/10.26418/jtllb.v10i1.48540

Luthfiyana, N., Ratrinia, P. W., Rukisah, Asniar, & Hidayat, T. (2022). Optimization of Demineralization Stage in Chitosan Extraction from Mangrove Crab Shell (Scylla sp.). Jurnal Pengolahan Hasil Perikanan Indonesia, 25(2), 352–363. https://doi.org/10.17844/jphpi.v25i2.41853

Mishra, S., Ren, Y., Sun, X., Lian, Y., Singh, A. K., & Sharma, N. (2024). Microplastics pollution in the Asian water tower: Source, environmental distribution and proposed mitigation strategy. Environmental Pollution, 356(April), 124247. https://doi.org/10.1016/j.envpol.2024.124247

Mulyani, R., Mulyadi, D., & Yusuf, N. (2019). Preparation and Characterization of Chitosan Membranes from Crab Shells (Scylla olivacea) for Beverage Preservative. Jurnal Kimia Valensi, 5(2), 242–247. https://doi.org/10.15408/jkv.v5i2.10637

Nouj, N., Majbar, Z., Abelouah, M. R., Ben Hamou, A., Chaoui, A., Hafid, N., Benafqir, M., El Alem, N., Jada, A., Ouachtak, H., Ait Addi, A., Buciscanu, I. I., Maier, V., Soreanu, G., & Cretescu, I. (2024). Eco-friendly wastewater treatment using a crab shell-based liquid bio-coagulant: Multi-criteria decision analysis related to different pollutants separation. Journal of Environmental Chemical Engineering, 12(2), 112318. https://doi.org/10.1016/j.jece.2024.112318

Sembiring, E. S., Widianingsih, W., & Supriyantini, E. (2022). Flokulasi Mikroalga Nannochloropsis oculata Menggunakan Kitosan dan pengoptimalan pH. Journal of Marine Research, 11(4), 752–757. https://doi.org/10.14710/jmr.v11i4.36241

Ugwu, K., Herrera, A., & Gómez, M. (2021). Microplastics in marine biota: A review. Marine Pollution Bulletin, 169(June). https://doi.org/10.1016/j.marpolbul.2021.112540

Uyanga, V. A., Ejeromedoghene, O., Lambo, M. T., Alowakennu, M., Alli, Y. A., Ere-Richard, A. A., Min, L., Zhao, J., Wang, X., Jiao, H., Onagbesan, O. M., & Lin, H. (2023). Chitosan and chitosan based composites as beneficial compounds for animal health: Impact on gastrointestinal functions and biocarrier application. Journal of Functional Foods, 104(January), 105520. https://doi.org/10.1016/j.jff.2023.105520

Wahab, F., Iber, B. T., Chik, C. E. N. C. E., Abdullah, S. R. S., Alianto, Aslamyah, S., & Kasan, N. A. (2023). Chitin and chitosan extraction: A comparison of three crab species from fresh, brackish and marine water environments. Bioresource Technology Reports, 23(June), 101517. https://doi.org/10.1016/j.biteb.2023.101517