Pengaruh Supporting Electrolyte terhadap Deteksi Ion Logam Pb(II) dan Cu(II) menggunakan PLE Termodifikasi Lapisan Tipis Perak dengan Metode Voltammetri Effect of Supporting Electrolyte on the Detection of Pb(II) and Cu(II) Metal Ions Using PLE Modified with Silver Thin Film by Voltammetry Method
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1933-1941
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10.58578/masaliq.v5i4.6738
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Authors:
Sisri Wartati1*, Trisna Kumala Sari2 
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Authors retain copyright and grant the journal right of first publication.
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Abstract
This study aims to evaluate the effect of different supporting electrolytes on the detection sensitivity of Pb(II) and Cu(II) ions simultaneously using a Pencil Lead Electrode (PLE) modified with a thin silver layer via electrodeposition. The modification was carried out using a 5 mM AgNO₃ solution in 0.1 M KNO₃ through cyclic voltammetry, producing reduction and oxidation peaks at +0.2256 V and +0.5253 V, respectively, indicating successful silver deposition on the electrode surface. The supporting electrolyte variations included 0.1 M solutions of HNO₃, H₂SO₄, and HClO₄, tested for 1 mM Pb(II) and Cu(II) ion analysis. The voltammogram results showed that 0.1 M HNO₃ yielded the highest current responses 1.3550 mA for Pb(II) and 1.3305 mA for Cu(II) making it the most optimal supporting electrolyte. These differences are attributed to the ionic mobility and diffusion rate of the species toward the electrode surface. The findings demonstrate that the choice of supporting electrolyte significantly influences the performance of electrochemical sensors. This research contributes to the development of efficient, cost-effective, and sensitive PLE-based sensors for simultaneous heavy metal detection.
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References
Afifah, R., & Sari, T. K. (2024). Pengaruh Supporting Electrolyte Terhadap Deteksi Ion Logam Pb2+ Menggunakan Pencil Lead Electrode Termodifikasi Lapisan Tipis Perak dengan Metode …. Jurnal Pendidikan Tambusai, 8, 17970–17976. https://jptam.org/index.php/jptam/article/view/14938%0Ahttps://jptam.org/index .php/jptam/article/download/14938/11406
Ahmed, A. S., Mohamed, M. B. I., Bedair, M. A., El-Zomrawy, A. A., & Bakr, M. F. (2023). A new Schiff base-fabricated pencil lead electrode for the efficient detection of copper, lead, and cadmium ions in aqueous media. RSC Advances, 13(23), 15651–15666. https://doi.org/10.1039/d3ra02582a
Alipour, E., Mirzae Bolali, F., Norouzi, S., & Saadatirad, A. (2022). Electrochemically activated pencil lead electrode as a sensitive voltammetric sensor to determine gallic acid. Food Chemistry, 375(August 2021), 131871. https://doi.org/10.1016/j.foodchem.2021.131871
Angizi, S., Hong, L., Huang, X., Selvaganapathy, P. R., & Kruse, P. (2023). Graphene versus concentrated aqueous electrolytes: the role of the electrochemical double layer in determining the screening length of an electrolyte. Npj 2D Materials and Applications, 7(1). https://doi.org/10.1038/s41699-023-00431-y
Annu, Sharma, S., Jain, R., & Raja, A. N. (2020). Review—Pencil Graphite Electrode: An Emerging Sensing Material. Journal of The Electrochemical Society, 167(3), 037501. https://doi.org/10.1149/2.0012003jes
Arce-Castro, J., Vilasó-Cadre, J. E., Benítez-Fernández, D., Rodríguez-de la Rosa, H., & Arada-Pérez, M. A. (2022). Effect of supporting electrolytes on voltammetry with manual staircase voltage scan. The Journal of Engineering and Exact Sciences, 8(3), 14235–01e. https://doi.org/10.18540/jcecvl8iss3pp14235-01e
Bedin, K. C., Mitsuyasu, E. Y., Ronix, A., Cazetta, A. L., Pezoti, O., & Almeida, V. C. (2018). Inexpensive Bismuth-Film Electrode Supported on Pencil-Lead Graphite for Determination of Pb ( II ) and Cd ( II ) Ions by Anodic Stripping Voltammetry. 2018.
David, I. G., Popa, D. E., & Buleandra, M. (2017). Pencil graphite electrodes: A versatile tool in electroanalysis. Journal of Analytical Methods in Chemistry, 2017(Cv). https://doi.org/10.1155/2017/1905968
Dickinson, E. J. F., Limon-Petersen, J. G., Rees, N. V., & Compton, R. G. (2009). How much supporting electrolyte is required to make a cyclic voltammetry experiment quantitatively ―diffusional‖? A theoretical and experimental investigation. Journal of Physical Chemistry C, 113(25), 11157–11171. https://doi.org/10.1021/jp901628
Ivanišević, I. (2023). The Role of Silver Nanoparticles in Electrochemical Sensors for Aquatic Environmental Analysis. Sensors, 23(7). https://doi.org/10.3390/s23073692
Jjagwe, J., Olupot, P. W., Kulabako, R., & Carrara, S. (2024). Electrochemical sensors modified with iron oxide nanoparticles/nanocomposites for voltammetric detection of Pb in water: A review. Heliyon, 10(8), e29743. https://doi.org/10.1016/j.heliyon.2024.e29743
Kumala Sari, T., Riga, R., & Zubir, M. (2021). Eksakta Article Pencil Lead Electrode Modified with Gold Thin Layer for Voltammetric Detection of Chromium(VI). Eksakta : Berkala Ilmiah Bidang MIPA, 22(2), 145–153. http://www.eksakta.ppj.unp.ac.id/index.php/eksakta
Liu, X., Yao, Y., Ying, Y., & Ping, J. (2019). Recent advances in nanomaterial-enabled screen printed electrochemical sensors for heavy metal detection. TrAC - Trends in Analytical Chemistry, 115, 187–202. https://doi.org/10.1016/j.trac.2019.03.021
Phal, S., Nguyễn, H., Berisha, A., & Tesfalidet, S. (2021). In situ Bi/carboxyphenyl-modified glassy carbon electrode as a sensor platform for detection of Cd2+ and Pb2+ using square wave anodic stripping voltammetry. Sensing and Bio-Sensing Research, 34(December 2022). https://doi.org/10.1016/j.sbsr.2021.100455
Pinate, S., Ispas, A., Leisner, P., & Zanella, C. (2021). Surface & Coatings Technology Electrocodeposition of Ni composites and surface treatment of SiC. Surface & Coatings Technology, 406(November 2020), 126663. https://doi.org/10.1016/j.surfcoat.2020.126663
Putri, Y. A., Sari, T. K., Oktavia, B., & Nizar, U. K. (2021). Pengaruh Supporting Electrolyte Pada Penentuan Formaldehida Secara Voltammetri Siklik Menggunakan Pencil Lead Electrode ( PLE ) Modifikasi Lapisan Tipis Perak. 10(1), 1–6.
Safavi, A., Maleki, N., & Farjami, E. (2009). Electrodeposited silver nanoparticles on carbon ionic liquid electrode for electrocatalytic sensing of hydrogen peroxide. Electroanalysis, 21(13), 1533–1538. https://doi.org/10.1002/elan.200804577
Saputri, L., & Marni, L. G. (2024). Analisis Kadar Timbal (Pb) Terlarut Pada Air Sungai Batanghari Kota Jambi Menggunakan Metode Spektrofotometri Serapan Atom (SSA). JSSIT: Jurnal Sains Dan Sains Terapan, 2(2), 18–25. https://doi.org/10.30631/jssit.v2i2.71
Sarvestani, M. R. J., Madrakian, T., & Afkhami, A. (2023). Simultaneous electrochemical determination of Pb2+ and Cu2+ ions in food samples by a silver nanoparticle-COF composite modified glassy carbon electrode. Journal of Food Measurement and Characterization, 3505–3514. https://doi.org/0.1007/s11694 023-01880-1
Zamhari, M., Hidayah, M. A., Tunjungsari, G. P., & Sedyadi, E. (2022). Electrochemical Detection of Pb(II) Using A Pencil Electrode with Square Wave Anodic Stripping Voltammetry Method. EduChemia (Jurnal Kimia Dan Pendidikan), 7(2), 150. https://doi.org/10.30870/educhemia.v7i2.14756