Pengaruh Penambahan Doping Cerium terhadap Nilai Bandgap CuO dengan Metode Sol-Gel The Influence of Cerium Doping on the Bandgap Value of CuO Using the Sol-Gel Method
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523-530
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10.58578/masaliq.v5i2.4873
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Authors:Yumanda Dwiputri1, Hary Sanjaya2, Miftah Patriela3
Copyright :Authors retain copyright and grant the journal right of first publication.
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Abstract
Copper(II) oxide (CuO) has been recognized as a promising semiconductor material for various applications, such as photocatalysis, sensors, and renewable energy devices. However, its efficiency is often limited by a suboptimal bandgap value. This study aims to analyze the effect of cerium doping on the properties of CuO nanoparticles synthesized through the sol-gel process. The sol-gel method ensures a homogeneous doping distribution and produces nanoparticles with a stable structure. The bandgap energy of CuO nanoparticles was determined through characterization using UV-DRS. Cerium was introduced as a dopant in CuO at a concentration of 0.4 mmol, resulting in a bandgap value of 1.26 eV, whereas undoped CuO exhibited a bandgap of 1.35 eV. The analysis indicates that the Ce doping concentration significantly affects the bandgap of CuO nanoparticles, with a reduction observed at 0.4 mmol compared to undoped CuO. This decrease is attributed to symmetry disruption caused by doping, including oxygen vacancies, structural defects, and the presence of impurities that create additional energy levels within the bandgap. Furthermore, uniform microstrain and a smaller particle size contribute to structural disturbances that also influence the bandgap.
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References
Anjelina, V., Sanjaya, H., & Budiman, S. (2024). Pengaruh Penambahan Monoethanolamine (MEA) Sebagai Aditif Dalam Sintesis dan Karakterisasi Lapisan Tipis Tembaga (II) Oksida (CuO). http://files/331/996.+Viony+Anjelina+9233-9238.pdf
Ansari, F., Sobhani, A., & Salavati-Niasari, M. (2018). Simple sol-gel synthesis and characterization of new CoTiO3/CoFe2O4 nanocomposite by using liquid glucose, maltose and starch as fuel, capping and reducing agents. Journal of Colloid and Interface Science, 514, 723–732. https://doi.org/10.1016/j.jcis.2017.12.083
Arandani, C. (2020). TUGAS AKHIR - TF 181801 PENGARUH DOPING Zn PADA CuO SEBAGAI FOTOKATODA DYE-SENSITIZED SOLAR CELL ( DSSC ) TIPE P PENGARUH DOPING Zn PADA CuO SEBAGAI FOTOKATODA DYE-SENSITIZED SOLAR CELL ( DSSC ) TIPE P.
Chopade, A. S., Kolhe, N. D., Walekar, L. S., Kadam, A. N., Patil, V. A., Al-Enizi, A. M., Tamboli, M. S., Mhamane, D. S., & Mali, M. G. (2024). Chemical bath assisted construction of CuO/BiVO4 p-n heterojunction photocatalyst for visible light driven rapid removal of MB and Cr(VI). Colloids and Surfaces A: Physicochemical and Engineering Aspects, 700, 134665. https://doi.org/10.1016/j.colsurfa.2024.134665
Dan, G. A. P., Listrik, K., & Tipis, L. (2024). M a s l i q. 4, 508–515.
Deotale, A. J., & Nandedkar, R. V. (2016). Correlation between Particle Size, Strain and Band Gap of Iron Oxide Nanoparticles. Materials Today: Proceedings, 3(6), 2069–2076. https://doi.org/10.1016/j.matpr.2016.04.110
Ilican, S., Caglar, Y., Caglar, M., & Yakuphanoglu, F. (2008). Structural, optical and electrical properties of F-doped ZnO nanorod semiconductor thin films deposited by sol–gel process. Applied Surface Science, 255(5), 2353–2359. https://doi.org/10.1016/j.apsusc.2008.07.111
Jońca, J., Ryzhikov, A., Palussière, S., Esvan, J., Fajerwerg, K., Menini, P., Kahn, M. L., & Fau, P. (2017). Organometallic Synthesis of CuO Nanoparticles: Application in Low‐Temperature CO Detection. ChemPhysChem, 18(19), 2658–2665. https://doi.org/10.1002/cphc.201700693
Kasuma Warda Ningsih, S., Kalmar Nizar, U., Bahrizal, B., Nasra, E., & Fatimah Mutiara R, S. (2021). Sintesis Mg2+ doped ZnO dengan penambahan albumen ayam ras menggunakan gabungan metode sol-gel dan sonokimia. Jurnal Riset Kimia, 12(1), 27–35. https://doi.org/10.25077/jrk.v12i1.374
Quirino, M. R., Lucena, G. L., de Araújo, R. J. C., da Silva, A. R., de Melo, A. M., dos Santos, I. M. G., & Gama, L. (2023). CuO and Ce-doped CuO Prepared by Microwave Hidrotermal Method in Photodegradation of Remazol Golden Yellow Dye. Materials Research, 26, 1–7. https://doi.org/10.1590/1980-5373-MR-2022-0300
Saini, K. K., Sharma, S. D., Chanderkant, Kar, M., Singh, D., & Sharma, C. P. (2007). Structural and optical properties of TiO2 thin films derived by sol–gel dip coating process. Journal of Non-Crystalline Solids, 353(24–25), 2469–2473. https://doi.org/10.1016/j.jnoncrysol.2006.12.017
Schiopu, A.-G., Iordache, D. M., Oproescu, M., Cursaru, L. M., & Ioța, A.-M. (2024). Tailoring the Synthesis Method of Metal Oxide Nanoparticles for Desired Properties. Crystals, 14(10), 899. https://doi.org/10.3390/cryst14100899
Singh, G. preet, Singh, J., Chandel, K., Arora, S., Singh, S., Singh, D., Batoo, K. M., Ijaz, M. F., Shirsath, S. E., Kaur, J., Singh, R. C., & Singh, K. J. (2024). Synthesis and characterization of pristine CuO and Mg/CuO nanostructures for their anti-breast cancer and photocatalytic degradation applications: Experimental and DFT investigations. Materials Today Communications, 40, 109398. https://doi.org/10.1016/j.mtcomm.2024.109398
Singh, S. J., & Chinnamuthu, P. (2021). Highly efficient natural-sunlight-driven photodegradation of organic dyes with combustion derived Ce-doped CuO nanoparticles. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 625(May), 126864. https://doi.org/10.1016/j.colsurfa.2021.126864
Sivayogam, D., Kartharinal Punithavathi, I., Jayakumar, S. J., & Mahendran, N. (2022). Structural, optical and electrical properties of Cd doped CuO nanoparticles obtained by simple sol gel method. Materials Today: Proceedings, 49, 2752–2757. https://doi.org/10.1016/j.matpr.2021.09.291