Pengaruh Perbandingan MAA dan EGDMA terhadap Kapasitas Adsorpsi IIPs-Pb(II) Effect of the Comparison of MAA and EGDMA on the Adsorption Capacity of IIPs-Pb(II)
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881-889
Digital Object Identifier:
10.58578/masaliq.v6i2.9370
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Authors:
Ananta Nazira Meliano1*, Alizar Ulianas2 
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Authors retain copyright and grant the journal right of first publication.
Main Article Content
Abstract
The successful synthesis of Ion Imprinted Polymers (IIPs) is strongly determined by the selection and ratio of the functional monomer and crosslinker because these two components directly affect the resulting adsorption capacity. An inappropriate composition, whether too low or too high, can reduce adsorption performance, because a low amount tends to produce a less stable polymer structure, whereas an excessive amount can increase nonspecific interactions and form an overly dense polymer structure. This study aims to determine the optimum ratio between the functional monomer and crosslinker in the synthesis of IIPs-Pb(II). The synthesis was carried out through the photopolymerization method by varying the amounts of MAA and EGDMA, then evaluating their performance based on the adsorption capacity toward Pb(II) metal ions. The concentration of adsorbed Pb(II) metal ions was analyzed using Atomic Absorption Spectroscopy (AAS). The results showed that the optimum ratio of MAA and EGDMA was 0.01 mol : 0.015 mol, with adsorption capacities of 0.79 mg/g and 0.43 mg/g, respectively. This optimum ratio was subsequently used to produce IIPs-Pb(II) that were effective in adsorbing Pb(II) metal ions. These findings contribute to clarifying the relationship between the composition of the functional monomer and crosslinker and the characteristics of the resulting polymer. Thus, IIPs-Pb(II) have the potential to be applied in the process of selectively detecting and removing Pb(II) metal ions, especially on an industrial scale.
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References
Alizar, U., Djaha, N. A., Mawardi, Suryani, O., Dewata, I., Safitri, E., Hidayat, N., Hanifah, S. A., & Hassan, R. A. (2025). Synthesis and characterization of molecularly imprinted polymers (MIPs) as adsorbents for methylene blue dye. Rasayan Journal of Chemistry, 18(1), 352–359. https://doi.org/10.31788/RJC.2025.1819126
Ao, X., & Guan, H. (2018). Preparation of Pb(II) ion-imprinted polymers and their application in selective removal from wastewater. Adsorption Science & Technology, 36(1–2), 774–787. https://doi.org/10.1177/0263617417722262
Cajamarca, F. A., & Tarley, C. R. T. (2022). Influence of synthesis parameters and polymerization methods on the selective and adsorptive performance of bio-inspired ion imprinted polymers. Separations, 9(10), Article 266. https://doi.org/10.3390/separations9100266
El Ouardi, Y., Giove, A., Laatikainen, M., Branger, C., & Laatikainen, K. (2021). Benefit of ion imprinting technique in solid-phase extraction of heavy metals, special focus on the last decade. Journal of Environmental Chemical Engineering, 9(6), Article 106548. https://doi.org/10.1016/j.jece.2021.106548
Febriani, A., Umaro, S. A., Nursa’adah, E., & Firdaus, M. L. (2022). Kapasitas Adsorpsi Zat Warna Malachite Green dan Violet Dye Menggunakan Metal Organic Frameworks (Fe-BDC). Hydrogen: Jurnal Kependidikan Kimia, 10(2), 61–72. https://doi.org/10.33394/hjkk.v10i2.5220
Haupt, K., Linares, A. V., Bompart, M., & Bui, B. T. S. (2012). Molecularly imprinted polymers. Topics in Current Chemistry, 325, 1–28. https://doi.org/10.1007/128_2011_307
Hong, D., Wang, C., Gao, L., & Nie, C. (2024). Fundamentals, synthetic strategies and applications of non-covalently imprinted polymers. Molecules, 29(15), Article 3555. https://doi.org/10.3390/molecules29153555
Kang, M. S., Cho, E., Choi, H. E., Amri, C., Lee, J. H., & Kim, K. S. (2023). Molecularly imprinted polymers (MIPs): Emerging biomaterials for cancer theragnostic applications. Biomaterials Research, 27, Article 45. https://doi.org/10.1186/s40824-023-00388-5
Kong, D., Qiao, N., Liu, H., Du, J., Wang, N., Zhou, Z., & Ren, Z. (2017). Fast and efficient removal of copper using sandwich-like graphene oxide composite imprinted materials. Chemical Engineering Journal, 326, 141–150. https://doi.org/10.1016/j.cej.2017.05.140
Kusumkar, V. V., Galamboš, M., Viglašová, E., Daňo, M., & Šmelková, J. (2021). Ion-imprinted polymers: Synthesis, characterization, and adsorption of radionuclides. Materials, 14(5), Article 1083. https://doi.org/10.3390/ma14051083
Lazar, M. M., Ghiorghita, C. A., Dragan, E. S., Humelnicu, D., & Dinu, M. V. (2023). Ion-imprinted polymeric materials for selective adsorption of heavy metal ions from aqueous solution. Molecules, 28(6), Article 2798. https://doi.org/10.3390/molecules28062798
Mueller, A. (2021). A note about crosslinking density in imprinting polymerization. Molecules, 26(17), Article 5139. https://doi.org/10.3390/molecules26175139
Nishchaya, K., Rai, V. K., & Bansode, H. (2023). Methacrylic acid as a potential monomer for molecular imprinting: A review of recent advances. Results in Materials, 18, Article 100379. https://doi.org/10.1016/j.rinma.2023.100379
Nitsae, M., Solle, H. R. L., Martinus, S. M., & Emola, I. J. (2021). Studi Adsorpsi Metilen Biru Menggunakan Arang Aktif Tempurung Lontar (Borassus flabellifer L.) Asal Nusa Tenggara Timur. Jurnal Kimia Riset, 6(1), 46–57. https://doi.org/10.20473/jkr.v6i1.24525
Pratama, K. F., Manik, M. E. R., Rahayu, D., & Hasanah, A. N. (2020). Effect of the molecularly imprinted polymer component ratio on analytical performance. Chemical & Pharmaceutical Bulletin, 68(11), 1013–1024. https://doi.org/10.1248/cpb.c20-00551
Ribas-Massonis, A., Cicujano, M., Duran, J., Besalú, E., & Poater, A. (2022). Free-radical photopolymerization for curing products for refinish coatings market. Polymers, 14(14), Article 2856. https://doi.org/10.3390/polym14142856
Tarley, C. R. T., Corazza, M. Z., Somera, B. F., & Segatelli, M. G. (2015). Preparation of new ion-selective cross-linked poly(vinylimidazole-co-ethylene glycol dimethacrylate) using a double-imprinting process for the preconcentration of Pb2+ ions. Journal of Colloid and Interface Science, 450, 254–263. https://doi.org/10.1016/j.jcis.2015.02.074
Vasapollo, G., Del Sole, R., Mergola, L., Lazzoi, M. R., Scardino, A., Scorrano, S., & Mele, G. (2011). Molecularly imprinted polymers: Present and future prospective. International Journal of Molecular Sciences, 12(9), 5908–5945. https://doi.org/10.3390/ijms12095908
Zhang, R., Gao, R., Gou, Q., Lai, J., & Li, X. (2022). Precipitation polymerization: A powerful tool for preparation of uniform polymer particles. Polymers, 14(9), Article 1851. https://doi.org/10.3390/polym14091851
Zhou, Z., Kong, D., Zhu, H., Wang, N., Wang, Z., Wang, Q., Liu, W., Li, Q., Zhang, W., & Ren, Z. (2018). Preparation and adsorption characteristics of an ion-imprinted polymer for fast removal of Ni(II) ions from aqueous solution. Journal of Hazardous Materials, 341, 355–364. https://doi.org/10.1016/j.jhazmat.2017.06.010