Sintesis Pigmen Merah Hematit (α-Fe2O3) dari Pasir Besi dengan Metode Kopresipitasi dan Hidrotermal: A Review
Synthesis of Hematite Red Pigment (α-Fe2O3) from Iron Sand via Coprecipitation and Hydrothermal Method: A Review
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2023-11-02
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10.58578/ajstea.v1i2.2036
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Abstract
The purified natural iron sand contains magnetic dioxide particles to produce ferric ions (Fe3+) which can be used as precursors for the synthesis of the red pigment hematite. Hematite red pigment synthesis was carried out by coprecipitation method with NaOH precipitating agent and hydrothermal.The optimum pH of the hematite red pigment synthesis reaction using the coprecipitation method is pH 6. At pH 6 it will produce a hematite red pigment with higher brightness. By the hydrothermal method Fe3O4 added 50 mL HCl (12,063 M) in a beaker. The filtrates are added boric acid with varying concentrations of 0.1 M; 0.3 m; 0.5 M and 1.0 M at a volume ratio of 1:1. Gradually the solution is supplemented with NH4OH 6 M until a solution with a pH of 8 is obtained at a constant temperature of 70oC. The formed precipitate is put in the microwave for 10 minutes with a pressure of 90P. The characterization was carried out using XRD to see the crystal structure of the product and UV-Vis to see the absorption wavelength.und is the anatase phase.
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Lestari, D. U. (2023). Sintesis Pigmen Merah Hematit (α-Fe2O3) dari Pasir Besi dengan Metode Kopresipitasi dan Hidrotermal: A Review. Asian Journal of Science, Technology, Engineering, and Art, 1(2), 255-265. https://doi.org/10.58578/ajstea.v1i2.2036
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References
Aini, S., Azra, F., & Cahyadi, A. (2020). The Characterization of West Sumatera Iron Sand as a Raw Material to Synthesize Magnetic Nanoparticles. Progress in Social Science, Humanities and Education Research Symposium, 5, 144–147. https://series.gci.or.id/article/362/16/psshers-2020
Al Hadi, F. H. (2010). PEMANFAATAN PASIR BESI DALAM SINTESIS HEMATITE (α-Fe2O3) SECARA HIDROTERMAL DENGAN VARIASI TEMPERATUR DAN WAKTU. Universitas Jember.
Ali, H. R., Nassar, H. N., & El-Gendy, N. S. (2017). Green synthesis of α-Fe2O3 using Citrus reticulum peels extract and water decontamination from different organic pollutants. Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 39(13), 1425–1434. https://doi.org/10.1080/15567036.2017.1336818
Ardhiati, F., & Muldarisnur, M. (2019). Pengaruh Konsentrasi Larutan Prekursor Terhadap Morfologi dan Ukuran Kristal Nanopartikel Seng Oksida. Jurnal Fisika Unand, 8(2), 133–138. https://doi.org/10.25077/jfu.8.2.133-138.2019
Chabib, M. N. (2017). Pengaruh Lama Kalsinasi pada Sintesis Senyawa Pigmen Hematit ((α-Fe2O3) dari Limbah Industri Kerajinan Besi dengan Metode Rute Presipitasi-Kalsinasi. Angewandte Chemie International Edition, 6(11), 951–952., 1–106.
Chiang, Y. H. (2019). Research and Application of Prussian Blue in Modern Science. IOP Conference Series: Earth and Environmental Science, 384(1). https://doi.org/10.1088/1755-1315/384/1/012005
Dwi Septityana, K., Taufiqu Rochman, N., Prastyo Rahman, T., Wahyu Nugroho, D., Ikono, R., & Nurwenda Novan, M. (2013). SINTESIS DAN KARAKTERISASI PIGMEN HEMATIT (α-Fe2O3) DARI BIJIH BESI ALAM MELALUI METODE PRESIPITASI. Youngster Physics Journal, 1(4), 95–100.
Fahlepy, M. R., Tiwow, V. A., & Subaer. (2018). Characterization of magnetite (Fe3O4) minerals from natural iron sand of Bonto Kanang Village Takalar for ink powder (toner) application. Journal of Physics: Conference Series, 997(1). https://doi.org/10.1088/1742-6596/997/1/012036
Fatmaliana, A., Maulinda, M., & Sari, N. (2020). SYNTHESIS AND CHARACTERIZATION OF HEMATITE (Fe2O3) OF IRON ORE AND MAGNETITE (Fe3O4) FROM IRON SAND THROUGH PRECIPITATION METHOD FOR INDUSTRIAL RAW MATERIALS. Jurnal Neutrino, 12(2), 37–42. https://doi.org/10.18860/neu.v12i2.8183.
Hartanto, R. S. W., & Dani, H. (2016). Studi Literatur: pengembangan media pembelajaran dengan software autocad. Jurnal Kajian Pendidikan Teknik Bangunan, 1(1), 1–6.
Khoiroh, L. M., Mardiana, D., Sabarudin, A., & Ismuyanto, B. (2013). Synthesis of Hematite Pigments (α-Fe 2 O 3 ) by Thermal Transformations of FeOOH. J. Pure App. Chem. Res, 2(1), 27–34. www.jpacr.ub.ac.id
MacHala, L., Tuček, J., & Zbořil, R. (2011). Polymorphous transformations of nanometric iron(III) oxide: A review. Chemistry of Materials, 23(14), 3255–3272. https://doi.org/10.1021/cm200397g
Mufti, N., Atma, T., Fuad, A., & Sutadji, E. (2014). Synthesis and characterization of black, red and yellow nanoparticles pigments from the iron sand. AIP Conference Proceedings, 1617(February 2015), 165–169. https://doi.org/10.1063/1.4897129
Nengsi, S. W., Budiman, A., & Puryanti, D. (2016). Karakterisasi Struktur Kristal dan Sifat Magnetik Maghemit (γ-Fe2O3) yang Dioksidasi dari Magnetit (Fe3O4 ) dari Pasir Besi Batang Sukam Kabupaten Sijunjung Sumatera Barat dengan Variasi Waktu Oksidasi. Jurnal Fisika Unand, 5(3), 248–251. https://doi.org/10.25077/jfu.5.3.248-251.2016
Prasetyo, A. B., Prasetiyo, P., & Matahari, I. (2014). Pembuatan α-Fe2O3 dari Hasil Pengolahan Bijih Besi Primer Jenis Hematit Untuk Bahan Baku Baterai Lithium. Majalah Metalurgi, 179–189.
Salomo, S., Erwin, E., Malik, U., & Putra, S. U. (2018). Sifat Magnetik Dan Ukuran Partikel Magnetik Serta Komposisi Material Pasir Besi Pantai Kata Pariaman Sumatera Barat Di Sintesa Dengan Iron Sand Separator Dan Ball Milling. Journal Online of Physics, 3(2), 11–14. https://doi.org/10.22437/jop.v3i2.5730
Saputra, F. M. A. (2017). SINTESIS PIGMEN MAGNETIK COPPER FERRITE (CuFe2O4) BERBAHAN DASAR PASIR BESI MENGGUNAKAN METODE KOPRESIPITASI. [Skripsi tidak diterbitkan]. Semarang : Universitas Negeri Semarang.
Sartini, Nurdin, M., & Agusu, L. (2013). SINTESIS HEMATIT BERPORI DARI PASIR BESI DENGAN METODE HIDROTERMAL SEBAGAI BAHAN ELEKTRODA BATERAI Li – ION. J. Prog. Kim. Si, 3(2), 97–107 .
Sholihah, L. K. (2010). SINTESIS DAN KARAKTERISTIK PARTIKEL NANO Fe 3 O 4 YANG BERASAL DARI PASIR BESI DAN Fe 3 O 4 BAHAN KOMERSIAL (ALDRICH). Http://Digilib.Its.Ac.Id/Public/ITS-Undergraduate-13315-Paper.Pdf.
Sulungbudi, G. T., Wildan, Z. L., & Salam, R. (2017). PENGENDALIAN SUHU ULTRASONIKASI PADA PELAPISAN NANOPARTIKEL MAGNET ( Fe 3 O 4 ) DENGAN KITOSAN. Jurnal Kimia Dan Kemasan, 39(2), 95–101. http://dx.doi.org/10.24817/jkk.v39i2.2838
Sunardi. (2009). Potency of use ferrous sulphate from iron waste workshop bubut for raw material pharmacy. Indonesian Journal of Pharmacy, 20(3), 151–155. https://doi.org/10.14499/indonesianjpharm0iss0pp151-155
Syukriani, H., Budiman, A., & Puryanti, D. (2017). Pengaruh Temperatur Sintering Terhadap Suseptibilitas Magnetik dan Struktur Stronsium Ferit (SrFe12O19) Pasir Besi Batang Sukam Kabupaten Sijunjung Sumatera Barat. Jurnal Fisika Unand, 6(3), 225–231. https://doi.org/10.25077/jfu.6.3.225-231.2017
Tati Suharti. (2017). Dasar-Dasar Spektrofotometri UV-VIS dan Spektrometri Massa untuk Penentuan Struktur Senyawa Organik. Bandar Lampung : Aura.
Wahyuni, Try, L., Wahyuni, & Try, L. (2022). Sintesis dan karakterisasi nanopartikel pigmen (biru) Prussian Blue Ferric(III) Hexacyanoferrate(II)(Fe4[Fe(CN)6]3) berbahan dasar pasir besi alam / Lilis Try Wahyuni. SKRIPSI Mahasiswa UM, 0(0). http://mulok.library.um.ac.id/index3.php/64716.html
Wu, W., Hao, R., Liu, F., Su, X., & Hou, Y. (2013). Single-crystalline α-Fe2O3 nanostructures: Controlled synthesis and high-index plane-enhanced photodegradation by visible light. Journal of Materials Chemistry A, 1(23), 6888–6894. https://doi.org/10.1039/c3ta10886d
Yang, X. J., Wang, S., Sun, H. M., Wang, X. B., & Lian, J. S. (2015). Preparation and photocatalytic performance of Cu-doped TiO2 nanoparticles. Transactions of Nonferrous Metals Society of China (English Edition), 25(2), 504–509. https://doi.org/10.1016/S1003-6326(15)63631-7.
Al Hadi, F. H. (2010). PEMANFAATAN PASIR BESI DALAM SINTESIS HEMATITE (α-Fe2O3) SECARA HIDROTERMAL DENGAN VARIASI TEMPERATUR DAN WAKTU. Universitas Jember.
Ali, H. R., Nassar, H. N., & El-Gendy, N. S. (2017). Green synthesis of α-Fe2O3 using Citrus reticulum peels extract and water decontamination from different organic pollutants. Energy Sources, Part A: Recovery, Utilization and Environmental Effects, 39(13), 1425–1434. https://doi.org/10.1080/15567036.2017.1336818
Ardhiati, F., & Muldarisnur, M. (2019). Pengaruh Konsentrasi Larutan Prekursor Terhadap Morfologi dan Ukuran Kristal Nanopartikel Seng Oksida. Jurnal Fisika Unand, 8(2), 133–138. https://doi.org/10.25077/jfu.8.2.133-138.2019
Chabib, M. N. (2017). Pengaruh Lama Kalsinasi pada Sintesis Senyawa Pigmen Hematit ((α-Fe2O3) dari Limbah Industri Kerajinan Besi dengan Metode Rute Presipitasi-Kalsinasi. Angewandte Chemie International Edition, 6(11), 951–952., 1–106.
Chiang, Y. H. (2019). Research and Application of Prussian Blue in Modern Science. IOP Conference Series: Earth and Environmental Science, 384(1). https://doi.org/10.1088/1755-1315/384/1/012005
Dwi Septityana, K., Taufiqu Rochman, N., Prastyo Rahman, T., Wahyu Nugroho, D., Ikono, R., & Nurwenda Novan, M. (2013). SINTESIS DAN KARAKTERISASI PIGMEN HEMATIT (α-Fe2O3) DARI BIJIH BESI ALAM MELALUI METODE PRESIPITASI. Youngster Physics Journal, 1(4), 95–100.
Fahlepy, M. R., Tiwow, V. A., & Subaer. (2018). Characterization of magnetite (Fe3O4) minerals from natural iron sand of Bonto Kanang Village Takalar for ink powder (toner) application. Journal of Physics: Conference Series, 997(1). https://doi.org/10.1088/1742-6596/997/1/012036
Fatmaliana, A., Maulinda, M., & Sari, N. (2020). SYNTHESIS AND CHARACTERIZATION OF HEMATITE (Fe2O3) OF IRON ORE AND MAGNETITE (Fe3O4) FROM IRON SAND THROUGH PRECIPITATION METHOD FOR INDUSTRIAL RAW MATERIALS. Jurnal Neutrino, 12(2), 37–42. https://doi.org/10.18860/neu.v12i2.8183.
Hartanto, R. S. W., & Dani, H. (2016). Studi Literatur: pengembangan media pembelajaran dengan software autocad. Jurnal Kajian Pendidikan Teknik Bangunan, 1(1), 1–6.
Khoiroh, L. M., Mardiana, D., Sabarudin, A., & Ismuyanto, B. (2013). Synthesis of Hematite Pigments (α-Fe 2 O 3 ) by Thermal Transformations of FeOOH. J. Pure App. Chem. Res, 2(1), 27–34. www.jpacr.ub.ac.id
MacHala, L., Tuček, J., & Zbořil, R. (2011). Polymorphous transformations of nanometric iron(III) oxide: A review. Chemistry of Materials, 23(14), 3255–3272. https://doi.org/10.1021/cm200397g
Mufti, N., Atma, T., Fuad, A., & Sutadji, E. (2014). Synthesis and characterization of black, red and yellow nanoparticles pigments from the iron sand. AIP Conference Proceedings, 1617(February 2015), 165–169. https://doi.org/10.1063/1.4897129
Nengsi, S. W., Budiman, A., & Puryanti, D. (2016). Karakterisasi Struktur Kristal dan Sifat Magnetik Maghemit (γ-Fe2O3) yang Dioksidasi dari Magnetit (Fe3O4 ) dari Pasir Besi Batang Sukam Kabupaten Sijunjung Sumatera Barat dengan Variasi Waktu Oksidasi. Jurnal Fisika Unand, 5(3), 248–251. https://doi.org/10.25077/jfu.5.3.248-251.2016
Prasetyo, A. B., Prasetiyo, P., & Matahari, I. (2014). Pembuatan α-Fe2O3 dari Hasil Pengolahan Bijih Besi Primer Jenis Hematit Untuk Bahan Baku Baterai Lithium. Majalah Metalurgi, 179–189.
Salomo, S., Erwin, E., Malik, U., & Putra, S. U. (2018). Sifat Magnetik Dan Ukuran Partikel Magnetik Serta Komposisi Material Pasir Besi Pantai Kata Pariaman Sumatera Barat Di Sintesa Dengan Iron Sand Separator Dan Ball Milling. Journal Online of Physics, 3(2), 11–14. https://doi.org/10.22437/jop.v3i2.5730
Saputra, F. M. A. (2017). SINTESIS PIGMEN MAGNETIK COPPER FERRITE (CuFe2O4) BERBAHAN DASAR PASIR BESI MENGGUNAKAN METODE KOPRESIPITASI. [Skripsi tidak diterbitkan]. Semarang : Universitas Negeri Semarang.
Sartini, Nurdin, M., & Agusu, L. (2013). SINTESIS HEMATIT BERPORI DARI PASIR BESI DENGAN METODE HIDROTERMAL SEBAGAI BAHAN ELEKTRODA BATERAI Li – ION. J. Prog. Kim. Si, 3(2), 97–107 .
Sholihah, L. K. (2010). SINTESIS DAN KARAKTERISTIK PARTIKEL NANO Fe 3 O 4 YANG BERASAL DARI PASIR BESI DAN Fe 3 O 4 BAHAN KOMERSIAL (ALDRICH). Http://Digilib.Its.Ac.Id/Public/ITS-Undergraduate-13315-Paper.Pdf.
Sulungbudi, G. T., Wildan, Z. L., & Salam, R. (2017). PENGENDALIAN SUHU ULTRASONIKASI PADA PELAPISAN NANOPARTIKEL MAGNET ( Fe 3 O 4 ) DENGAN KITOSAN. Jurnal Kimia Dan Kemasan, 39(2), 95–101. http://dx.doi.org/10.24817/jkk.v39i2.2838
Sunardi. (2009). Potency of use ferrous sulphate from iron waste workshop bubut for raw material pharmacy. Indonesian Journal of Pharmacy, 20(3), 151–155. https://doi.org/10.14499/indonesianjpharm0iss0pp151-155
Syukriani, H., Budiman, A., & Puryanti, D. (2017). Pengaruh Temperatur Sintering Terhadap Suseptibilitas Magnetik dan Struktur Stronsium Ferit (SrFe12O19) Pasir Besi Batang Sukam Kabupaten Sijunjung Sumatera Barat. Jurnal Fisika Unand, 6(3), 225–231. https://doi.org/10.25077/jfu.6.3.225-231.2017
Tati Suharti. (2017). Dasar-Dasar Spektrofotometri UV-VIS dan Spektrometri Massa untuk Penentuan Struktur Senyawa Organik. Bandar Lampung : Aura.
Wahyuni, Try, L., Wahyuni, & Try, L. (2022). Sintesis dan karakterisasi nanopartikel pigmen (biru) Prussian Blue Ferric(III) Hexacyanoferrate(II)(Fe4[Fe(CN)6]3) berbahan dasar pasir besi alam / Lilis Try Wahyuni. SKRIPSI Mahasiswa UM, 0(0). http://mulok.library.um.ac.id/index3.php/64716.html
Wu, W., Hao, R., Liu, F., Su, X., & Hou, Y. (2013). Single-crystalline α-Fe2O3 nanostructures: Controlled synthesis and high-index plane-enhanced photodegradation by visible light. Journal of Materials Chemistry A, 1(23), 6888–6894. https://doi.org/10.1039/c3ta10886d
Yang, X. J., Wang, S., Sun, H. M., Wang, X. B., & Lian, J. S. (2015). Preparation and photocatalytic performance of Cu-doped TiO2 nanoparticles. Transactions of Nonferrous Metals Society of China (English Edition), 25(2), 504–509. https://doi.org/10.1016/S1003-6326(15)63631-7.
