Synthesis and Characterisation of Calcined Zeolite X and Silica-Supported Zeolite Y
Digital Object Identifier:
10.58578/ajstm.v1i1.3493
Article Metrics:
Viewed : 32 times
Downloaded : 20 times
Viewed : 32 times
Downloaded : 20 times
Article can trace at:
Author Fee:
Free Publication Fees for Foreign Researchers (0.00)
Connected Papers:
Please do not hesitate to contact us if you would like to obtain more information about the submission process or if you have further questions.
Abstract
Zeolite X was synthesised from rice husk silica and aluminium metal as raw materials while Zeolite Y supported catalyst was synthesised from sodium hydroxide, sodium silicate and alumina as chemical raw materials and was impregnated with rice husk silica by wet impregnation method, the catalyst were subsequently calcined at 550 0C for 6h the catalysts were characterised using XRD, FTIR and SEM. The formation of AlO4/SiO4 catalyst was confirmed by the analysis aforementioned. The XRD revealed that Zeolite X and Y synthesized has a faujasite phase with major peaks 230, 22.50 and 17.50, 180 in zeolite X and Y respectively, SEM confirmed the composition of crystallite shapes of irregular, cubic and rectangular shape. FTIR analyses revealed the presence of functional groups (The signal at the silica-alumina vibrational regions (1300 – 300 cm-1) indicates that SiO4 or AlO4 are linked) associated with Zeolites.
Keywords:
Zeolite X; Zeolite Y; Calcined; Impregnation; Rice Husk Silica
Share Article:
Citation Metrics:
Downloads
Download data is not yet available.
How to Cite
M, A. A., L, L., M, T. S., T, J., J, E. O., & P, O. O. (2024). Synthesis and Characterisation of Calcined Zeolite X and Silica-Supported Zeolite Y. African Journal of Sciences and Traditional Medicine, 1(1), 157-168. https://doi.org/10.58578/ajstm.v1i1.3493
Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
References
Abakpa, A. M., Magomya, A. M., Yebpella, G. G., & Japhet, T. (2023). Assessment of heavy metal concentration in soil around Owukpa coal mine field, North Central Nigeria. Journal of Biological Pharmaceutical and Chemical Research, 10(3), 1-10.
Chen, K., Wu, X., Zhao, J., Zhao, H., Li, A., Zhang, Q., & Shen, B. (2022b). Organic-free modulation of the framework Al distribution in ZSM-5 zeolite by magnesium participated synthesis and its impact on the catalytic cracking reaction of alkanes. Journal of Catalysis, 413, 735-750.
Chen, L., Ren, S., Jiang, Y., Liu, L., Wang, M., Yang, J., & Liu, Q. (2022a). Effect of Mn and Ce oxides on low-temperature NH3-SCR performance over blast furnace slag-derived zeolite X supported catalysts. Fuel, 320, 123969.
Daligaux, V., Richard, R., & Manero, M. H. (2021). Deactivation and regeneration of zeolite catalysts used in pyrolysis of plastic wastes—A process and analytical review. Catalysts, 11(770).
Darlington, N. J., Oke, E. O., & Edoga, M. O. (2021). Synthesis and characterization of zeolite y from Ukpor clay from Anambra State, Nigeria. Acta Technica Corviniensis-Bulletin of Engineering, 14(2), 105-110.
Garcia, J., & Lopez, M. (2017). Pore structure in zeolite X. Materials Science and Engineering, 58(1), 89-102.
García, M. A., Rodríguez, M., Castro, C., & De La Paz, N. (2020). Water vapor permeability of chitosan/zeolite composite films as affected by biopolymer and zeolite microparticle concentrations. Journal of Packaging Technology and Research, 4, 157-169.
Giuberti, G., Rocchetti, G., & Lucini, L. (2020). Interactions between phenolic compounds, amylolytic enzymes and starch: An updated overview. Current Opinion in Food Science, 31, 102-113.
Gribbin, J. (2023). Computing with Quantum Cats: The History, Theory, and Application of a Revolutionary Science. Rowman & Littlefield.
Hasanah, M., Sembiring, T., Sitorus, Z., Humaidi, S., & Zebua, F. (2022). Extraction and characterization of silicon dioxide from volcanic ash of mount Sinabung, Indonesia: A preliminary study. Journal of Ecological Engineering, 23(3).
Jambhulkar, D. K., Ugwekar, R. P., Bhanvase, B. A., & Barai, D. P. (2022). A review on solid base heterogeneous catalysts: Preparation, characterization and applications. Chemical Engineering Communications, 209(4), 433-484.
Jiang, J., Zhang, S., Longhurst, P., Yang, W., & Zheng, S. (2021). Molecular structure characterization of bituminous coal in Northern China via XRD, Raman and FTIR spectroscopy. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 255, 119724.
Jones, M., & Brown, A. (2018). Study of particle agglomeration in zeolite samples. Spectroscopy Letters, 51(2), 111-125.
Keil, H., Herbst-Irmer, R., Rathjen, S., Girschik, C., Müller, T., & Stalke, D. (2022). Si–H··· Se chalcogen–hydride bond quantified by diffraction and topological analyses. Inorganic Chemistry, 61(16), 6319-6325.
Li, J., & Wang, H. (2016). Research identifying SiO₃ peaks in zeolite X and their comparison with standard XRD patterns. Journal of Material Science Research, 5(2), 123-135.
Martinez, T., & Wang, H. (2020). Structural analysis of zeolite samples. Journal of Structural Chemistry, 61(3), 789-801.
Murukutti, M. K., & Jena, H. (2022). Synthesis of nano-crystalline zeolite-A and zeolite-X from Indian coal fly ash, its characterization and performance eval_uation for the removal of Cs+ and Sr2+ from simulated nuclear waste. Journal of Hazardous Materials, 423, 127085.
Nakhaei Pour, A., & Mohammadi, A. (2021). Effects of synthesis parameters on organic template-free preparation of zeolite Y. Journal of Inorganic and Organometallic Polymers and Materials, 31(6), 2501-2510.
Opoku, F., Aniagyei, A., Akoto, O., Kwaansa-Ansah, E. E., Asare-Donkor, N. K., & Adimado, A. A. (2022). Effect of van der Waals stacking in CdS monolayer on enhancing the hydrogen production efficiency of SiH monolayer. Materials Advances, 3(11), 4629-4640.
Sawasdee, V., & Pisutpaisal, N. (2022). Rice husk ash characterization and utilization as a source of silica material. Chemical Engineering Transactions, 93, 79-84.
Sayehi, M., Delahay, G., & Tounsi, H. (2022). Synthesis and characterization of ecofriendly materials zeolite from waste glass and aluminum scraps using the hydrothermal technique. Journal of Environmental Chemical Engineering, 10(6), 108561.
Simpson, L., & Lee, C. (2018). Morphological analysis of zeolite grains. Zeolite Research, 22(1), 78-92.
Smith, A. T., Plessow, P. N., & Studt, F. (2021). Trends in the reactivity of proximate aluminum sites in H-SSZ-13. The Journal of Physical Chemistry C, 125(30), 16508-16515.
Souza, I. M., Borrego-Sánchez, A., Sainz-Díaz, C. I., Viseras, C., & Pergher, S. B. (2021). Study of Faujasite zeolite as a modified delivery carrier for isoniazid. Materials Science and Engineering: C, 118, 111365.
Vogt, C., & Weckhuysen, B. M. (2022). The concept of active site in heterogeneous catalysis. Nature Reviews Chemistry, 6(2), 89-111.
Wang, Y., Zhang, R., Zhao, X., Min, Y., & Liu, C. (2020). Structural transformation of molten CaO–SiO₂–Al₂O₃–FexO slags during secondary refining of steels. ISIJ International, 60(2), 220-225.
Chen, K., Wu, X., Zhao, J., Zhao, H., Li, A., Zhang, Q., & Shen, B. (2022b). Organic-free modulation of the framework Al distribution in ZSM-5 zeolite by magnesium participated synthesis and its impact on the catalytic cracking reaction of alkanes. Journal of Catalysis, 413, 735-750.
Chen, L., Ren, S., Jiang, Y., Liu, L., Wang, M., Yang, J., & Liu, Q. (2022a). Effect of Mn and Ce oxides on low-temperature NH3-SCR performance over blast furnace slag-derived zeolite X supported catalysts. Fuel, 320, 123969.
Daligaux, V., Richard, R., & Manero, M. H. (2021). Deactivation and regeneration of zeolite catalysts used in pyrolysis of plastic wastes—A process and analytical review. Catalysts, 11(770).
Darlington, N. J., Oke, E. O., & Edoga, M. O. (2021). Synthesis and characterization of zeolite y from Ukpor clay from Anambra State, Nigeria. Acta Technica Corviniensis-Bulletin of Engineering, 14(2), 105-110.
Garcia, J., & Lopez, M. (2017). Pore structure in zeolite X. Materials Science and Engineering, 58(1), 89-102.
García, M. A., Rodríguez, M., Castro, C., & De La Paz, N. (2020). Water vapor permeability of chitosan/zeolite composite films as affected by biopolymer and zeolite microparticle concentrations. Journal of Packaging Technology and Research, 4, 157-169.
Giuberti, G., Rocchetti, G., & Lucini, L. (2020). Interactions between phenolic compounds, amylolytic enzymes and starch: An updated overview. Current Opinion in Food Science, 31, 102-113.
Gribbin, J. (2023). Computing with Quantum Cats: The History, Theory, and Application of a Revolutionary Science. Rowman & Littlefield.
Hasanah, M., Sembiring, T., Sitorus, Z., Humaidi, S., & Zebua, F. (2022). Extraction and characterization of silicon dioxide from volcanic ash of mount Sinabung, Indonesia: A preliminary study. Journal of Ecological Engineering, 23(3).
Jambhulkar, D. K., Ugwekar, R. P., Bhanvase, B. A., & Barai, D. P. (2022). A review on solid base heterogeneous catalysts: Preparation, characterization and applications. Chemical Engineering Communications, 209(4), 433-484.
Jiang, J., Zhang, S., Longhurst, P., Yang, W., & Zheng, S. (2021). Molecular structure characterization of bituminous coal in Northern China via XRD, Raman and FTIR spectroscopy. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 255, 119724.
Jones, M., & Brown, A. (2018). Study of particle agglomeration in zeolite samples. Spectroscopy Letters, 51(2), 111-125.
Keil, H., Herbst-Irmer, R., Rathjen, S., Girschik, C., Müller, T., & Stalke, D. (2022). Si–H··· Se chalcogen–hydride bond quantified by diffraction and topological analyses. Inorganic Chemistry, 61(16), 6319-6325.
Li, J., & Wang, H. (2016). Research identifying SiO₃ peaks in zeolite X and their comparison with standard XRD patterns. Journal of Material Science Research, 5(2), 123-135.
Martinez, T., & Wang, H. (2020). Structural analysis of zeolite samples. Journal of Structural Chemistry, 61(3), 789-801.
Murukutti, M. K., & Jena, H. (2022). Synthesis of nano-crystalline zeolite-A and zeolite-X from Indian coal fly ash, its characterization and performance eval_uation for the removal of Cs+ and Sr2+ from simulated nuclear waste. Journal of Hazardous Materials, 423, 127085.
Nakhaei Pour, A., & Mohammadi, A. (2021). Effects of synthesis parameters on organic template-free preparation of zeolite Y. Journal of Inorganic and Organometallic Polymers and Materials, 31(6), 2501-2510.
Opoku, F., Aniagyei, A., Akoto, O., Kwaansa-Ansah, E. E., Asare-Donkor, N. K., & Adimado, A. A. (2022). Effect of van der Waals stacking in CdS monolayer on enhancing the hydrogen production efficiency of SiH monolayer. Materials Advances, 3(11), 4629-4640.
Sawasdee, V., & Pisutpaisal, N. (2022). Rice husk ash characterization and utilization as a source of silica material. Chemical Engineering Transactions, 93, 79-84.
Sayehi, M., Delahay, G., & Tounsi, H. (2022). Synthesis and characterization of ecofriendly materials zeolite from waste glass and aluminum scraps using the hydrothermal technique. Journal of Environmental Chemical Engineering, 10(6), 108561.
Simpson, L., & Lee, C. (2018). Morphological analysis of zeolite grains. Zeolite Research, 22(1), 78-92.
Smith, A. T., Plessow, P. N., & Studt, F. (2021). Trends in the reactivity of proximate aluminum sites in H-SSZ-13. The Journal of Physical Chemistry C, 125(30), 16508-16515.
Souza, I. M., Borrego-Sánchez, A., Sainz-Díaz, C. I., Viseras, C., & Pergher, S. B. (2021). Study of Faujasite zeolite as a modified delivery carrier for isoniazid. Materials Science and Engineering: C, 118, 111365.
Vogt, C., & Weckhuysen, B. M. (2022). The concept of active site in heterogeneous catalysis. Nature Reviews Chemistry, 6(2), 89-111.
Wang, Y., Zhang, R., Zhao, X., Min, Y., & Liu, C. (2020). Structural transformation of molten CaO–SiO₂–Al₂O₃–FexO slags during secondary refining of steels. ISIJ International, 60(2), 220-225.
