Green Synthesis, Structural Characterization and Study of Thermal Behaviour of Cu2+ and Co2+ Complexes Derived from Salicylidene-3-Amino Benzoic Acid
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10.58578/amjsai.v1i1.3741
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Abstract
The Schiff base ligand Salicylidene-3-amino benzoic acid (SAB) was prepared by reacting salicylaldehyde with 3-amino benzoic acid. Its Cu2+ and Co2+ complexes were prepared by reacting ethanolic solutions of SAB with magnetically stirred solution of metal salts in distilled water using microwave-assisted heating for 30 min. The ligand and complexes were characterized on the basis of physical properties, FT-IR, UV-Vis, magnetic susceptibility, XRD and TGA/DTA. Unit cell dimensions obtained from XRD crystallography analysis agreed with the establishment of orthorhombic crystal structure. The spectroscopic studies revealed the presence of -C=N, -C=O, M-O, M-N, -OH and NO3 functional groups and this showed that the ligand coordinated to metal via N and O donors. The thermal decomposition of the complexes indicates the loss of lattice of water and decomposition of the ligand as key to the interpretation of successive weight loss.
Keywords:
Characterization; Coordination; Metal complexes; Salicylaldehyde; Schiff base
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O, A. S., A, W. R., R, S., & S, E. I. (2024). Green Synthesis, Structural Characterization and Study of Thermal Behaviour of Cu2+ and Co2+ Complexes Derived from Salicylidene-3-Amino Benzoic Acid. African Multidisciplinary Journal of Sciences and Artificial Intelligence, 1(1), 620-633. https://doi.org/10.58578/amjsai.v1i1.3741
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Shamly, P., Mary, P. N., Anitta, A. and Jaya, T. V. (2018). Synthesis of salicylaldehyde based schiff bases and their metal complexes in aqueous media -characterization and antibacterial study. International Journal of Recent Scientific Research, 9(5B): 26566-26570.
Vijayalakshmi, M. (2018). Synthesis and Spectral Characterization of Schiff Base Transition Metal Complexes, DNA Cleavage and Antibacterial Activity Studies. Rasayan Journal of Chemistry, 11(2): 857-864.
Zhai, C., Cui, F., and Liu, X. (2015). A combined experimental and theoretical study on vibrational spectra of 2-acetylpyridine. Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 134: 90-95.
Asep, B.N., Rosi O. and Risti, R. (2019). How to Read and Interpret FTIR Spectroscope of Organic Material. Indonesian Journal of Science and Technolgy, 4(1):97-118.
Basim, H.A., Mohammed M.H., and Ahmad H.I (2019). New complexes of chelating Schiff base: Synthesis, spectral investigation, antimicrobial, and thermal behavior studies. Journal of Applied Pharmaceutical Science. 9(04):45-57.
Chandrasekaran, T., Suresh, M., Ahamed, F.M.A. and Padusha, M.S.A. (2014). Synthesis, characterization and antimicrobial studies of novel compound and its metal complexes derived from nicotinic acid. Der Chemica Sinica, 5: 81-90.
Dudhat, R.S. and Kulkarni, S. (2018). Application of Schiff bases and their metal complexes as insecticides and plant growth regulators-A review. International Journal of Engineering Technology Science and Research, 5(3): 740743.
Dnyandeo, M.J., Dingambar D.G., Priyanka, L.A. and Ganesh, S.K. (2015). Efficient Ultrasound Synthesis and Biological Screening of Metal Complexes of N-(4-Methoxybenzylidiene) isonicotinohydrazone. World Journal of Pharmaceutical Research, 5(2): 1153-1161.
Ejidike, I.P. (2016). Synthesis, Characterization and in vitro Biological Studies of Metal Schiff Bases. Ph.D thesis. Department of Chemistry, University of Fort Hare. 221 pp.
Fugu, M.B., Ndahi, N.P., Paul, B.B and Mustapha, A.N. (2013). Synthesis, characterization and antimicrobial studies of some vanillin Schiff base metal (II) complexes. Journal of Chemical and Pharmaceutical Research, 5: 22-28.
Grace E. Iniama, Lorkpiligh, I.T., Olajire, S. O., Dooshima, S. and Kondom, M.I. (2015). Synthesis, characterization and antibacterial studies of Mn(II), Co(II) and Zn(II) Sciff base complexes derived from glycine and 2-hydroxy-1-Naphthaldehyde. International Journal of Innovation and Scientific Research, 18(1): 117-121.
Iorungwa, M.S, Wuana, A.R, Tyagher, L., Agbendeh, Z.M, Iorungwa P.D, Surma, N and Amua Q.M. (2020). Synthesis, Characterization, Kinetics, Thermodynamics and Nematicidal Studies of Sm(III), Gd(III) and Nd(III) Schiff Base Complexes. ChemSearch Journal. 11(2): 24-34.
Kadhiravansivasamy, K, Sivajiganesan, S., Periyathambi, Nandhakumar, V., Chidhambram, S. and Manimekalai, R. (2017). Synthesis and characterization of Schiff base CoII, NiII and CuII complexes derived from 2-Hydroxy-1-naphthaldehyde and 2-Picolylamine. Modern Chemistry and Applications, 5:1-6.
Kiran, S., Ritu, T.H. and Vikas, K. (2016). Co(II), Ni(II), Cu(II) and Zn(II) complexes derived from 4-[{3-(4-bromophenyl)-1-phenyl-1Hpyrazol-4-ylmethylene}-amino]-3-mercapto-6-methyl-5-oxo-1,2,4-triazine. Elsevier Journal of Basic and Appied Sciences, 5: 21-30
Lekha, L. (2014). Studies on the synthesis, characterisation and antimicrobial applications of rare earth metal Schiff base complexes. Ph.D. thesis. B.S. Abdur Rahman Institute of Science & Technology, B.S. Abdur Rahman University, India. 252 pp.
Muayed, A. R. (2012). Synthesis, Spectroscopic and Antibacterial Studies of Zinc(II) complexes derived from Salicyladehyde, Leucyalanine and Glycylglycine. Baghdad Science Journal, 9(3): 532-54.
Palanimurugan, A., Sudharkani, V. and Kukandaisamy, A. (2016). Synthesis, spectral, redox and antimicrobial activities of mixed ligand complexes derived from 1-Phenyl-2,3-dimethyl-4-imino-benzylidene-pyrazol-5-one and dimethylglyoxime. Journal of Nanoscience and Technology, 2(5): 204-208.
Pallavi, G., Dinesh, K. and Sulekh, C. (2014). A photochemical dehydrogenative strategy for aniline synthesis. Journal of Chemical, Biological and Physical Sciences, 4(3): 1946-1964.
Rahman, A.M. (2022). Synthesis, characterization and antibacterial of Schiff base salicylidene meta-aminobenzoic acid and its metal complexes of Cu(II), Pb(II) , Zn(II), Mn(II), Cd(II), Hg(II), Ni(II) and Fe(III). AIP conference proceedings, 2394, 040006.
Rishu, K., Harpreet, K. and Brij, K. K. (2013). Applications of Copper- Schiffs base complexes: a review. Scientific Reviews and Chemical Communications, 3(1), 1-15.
Salawu, O.W. and Aliyu, O.C. (2012). Synthesis, Spectral Studies of Metal(II) Complexes. Advances in Pure and Applied Chemistry (APAC), 1(1), 1217.
Salga, M.S., Yusuf, M.M. and Usman, U.S. (2018). Synthesis and eval_uation of the efficacies of some Schiff bases for the removal of heavy metals from wastewater. Science World Journal, 13(4): 108-114.
Shamly, P., Mary, P. N., Anitta, A. and Jaya, T. V. (2018). Synthesis of salicylaldehyde based schiff bases and their metal complexes in aqueous media -characterization and antibacterial study. International Journal of Recent Scientific Research, 9(5B): 26566-26570.
Vijayalakshmi, M. (2018). Synthesis and Spectral Characterization of Schiff Base Transition Metal Complexes, DNA Cleavage and Antibacterial Activity Studies. Rasayan Journal of Chemistry, 11(2): 857-864.
Zhai, C., Cui, F., and Liu, X. (2015). A combined experimental and theoretical study on vibrational spectra of 2-acetylpyridine. Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 134: 90-95.
